What are
the limitations imposed by materials on thermal power plants achieving the
highest efficiency and output at the lowest cost? How to get over these
limitations? Read on...
Laws of Thermodynamics
- You cannot win, you can only
break even.
- You can only break even at
absolute zero.
- You cannot reach absolute
zero.
The
thermodynamic cycle used in a Thermal Power plant utilises steam at high
temperatures and pressures. Increasing the upper temperature and pressure
limits of the thermodynamic cycle increases the efficiency of the cycle. Power
Plants operating with steam parameters of 540 °C and 170 bar pressure have an
efficiency of 38 % while Ultra super critical power plants with
steam parameters of 300 bar and 620 °C can have efficiencies of 48 %. This
increase in efficiency is a direct emissions reduction apart from the cost
savings.
Why are
the older power plants operating at a lower temperature and
pressure? Why are power plants with higher temperatures greater than 615 °C not
made? This is because of the limitations imposed by the materials used for
making the tubes, drums, and pipes which contain and transport the steam.
Limitations
The
limitations in material are due to
- Reduction
in strength.
- The mechanical strength
properties of steel drastically reduce with increased temperatures. This
means to withstand the higher pressure, the thickness of the tubes and
pipes have to be increased.
- Added to this the continued
operation at high pressure and temperatures leads to creep or slow
degradation in the mechanical strength properties.
- Increased thickness means
higher thermal stresses which imposes severe limitations on the design
engineers. Also increased thickness means higher weight, meaning more
structures and foundations, all leading to design limitations and higher
cost.
- Oxidation.
- At higher temperatures, due
to oxidation, scales form on the tube material. This in the continuous
operation effect the life of the plant. Oxidation limit for Carbon steels
is around 425 °C.As the steam and gas temperatures increase above the
this limit, special alloy steels have to be used to prevent oxidation.
To
overcome these limitations newer and newer materials are developed. Two decades
ago the tube material for carrying the Superheated steam was grade T22 or P22
which had an allowable stress value of 50 N/mm² at 570 °C. At 600 °C it reduces
drastically to 34 N /mm². Today we use grade T91 or P91 that has strength of 78
N/mm² at 570 °C and 60 N/mm² at 600 °C. This relates to a 40 % reduction in
thickness at 570 °C.
The
difference is the addition of alloying elements to the basic Carbon Steel.
Grade P22 has 2.0 % Chromium and 1 % Molybdenum whereas Grade P9 has 9 %
Chromium and 1 % Molybdenum, Nickel, and Vanadium.
For the
high temperature application these special steels are called creep resistant
steels. These are derived from the normal Carbon steels by adding alloy
elements that increase the mechanical strength and heat resistant properties.
The five
criteria that the industry is looking for in developing new materials are:
- Mechanical strength of the material
should be available at higher temperatures.
- Mechanical strength
properties should be consistent throughout the life of the plant at these
elevated operating conditions or it should be creep resistant.
- The materials should be
easily produced and available.
- The materials should be easy
for fabrication and construction.
- All this at a reasonable
cost for investment.
But the
most important thing is that this allows the power plants to operate at higher
temperatures and pressure which means higher efficiency and lower emissions.
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